The “Exalted Argent Champion of the Alliance” achievement is bugged, as reward it should unlock the Argent Tournament dailies and the vendors on all alliance characters.
WoWHead says only that you’ll get the Crusader title but the in-game description is: “Title Reward: Crusader. Unlocks Crusader dailies at the Argent Tournament.”
(The Title reward works but the daily quest unlock is bugged.)