I recommend you do the following, and only the following (for your own good):
1.) Check your mission table at least one time per day and do every single Voldunai rep mission. Save your followers so you can get it to 200% or as close as possible each time.
2.) Do the emissary when it’s up.
And that’s it. It won’t take as long as you think, and you’ll be happy and sane at the end of it.
IF–and it’s a big if–you want it faster and are looking to do EVERYTHING you can do each day; here is the list:
1.) Go to the Auction House and buy a Voldunai contract. Use it. For the next week, every WQ you do will give you 10 Voldunai rep on top of the normal rep it would give.
(ex. You do a Tortollan World Quest that gives 150 Tortollan Rep. With the contract, it will give you 150 Tortollan Rep plus 10 Voldunai Rep. If you do a World Quest for the Voldunai, it will give you the normal rep plus a line item of 10 more). If you do every WQ on the map every day, this adds up.
2.) Do every Voldunai quest on the map every day. It’s not that many. I chose to do it that way, and it was less than an hour per day. If you’ve got a contract, do every WQ you can stomach doing from every zone in the BfA content (including Nazjatar and Mechagon).
3.) Be vigilant about your mission table (check it more than once per day) and do every mission that comes up for Voldunai reputation. Save all your followers through the day so that you don’t have any tied up on non-Voldunai quests that you need when they pop up. At night before sleep, do every mission on the table that runs less than 8 hours to prompt more cycling of missions by clearing it out. When you get up the next day, all your followers will be free to start afresh. Repeat until exalted.
4.) Make sure you have done every story quest in the Voldun zone–there are a few scattered around that aren’t requirements for the achievement. Really look at it and see. Get on WoWhead or a similar data site and look up the quests that give Voldunai reputation. You probably missed one or two somewhere, and every little helps.
5.) Emissaries…Obviously, you don’t want to miss any.
I went from nothing to halfway through honored by doing the zone thoroughly. After that, I did most of the above, but I did it during the reputation event (which is now over). The ONLY reason I pushed it that hard was to save myself time in the long run by getting it done during the reputation bonus event.
I don’t recommend pushing that hard because it will be grindy and boring. If you just do all the table missions and the emissaries when they cycle in, you’ll have it in no time and no stress or grinding or boredom or resentment will be necessary.
Oh, and yes. The Voldunai are worth it.