Hi, where/how can I start to gather PvP gear?
“PvP gear” is basically just cosmetic now, and can only be obtained as usable gear randomly through instanced PvP. Different ranks of PvP will offer different appearances.
If you’re looking to gear up for PvP purposes, your sources are the same as PvE. Do WQs, dungeons, and raids.
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For details on pvp gear, check out the following link. I just answered this exact question a couple days ago. Everything you need to know is in there. 
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