DPS:
-Genji: Slice and Dice and Their Own Worst Enemy (I don’t play Genji.)
-Pharah: Death From Above (Ditto on Pharah.)
-Soldier 76: Rocket Man (He’s one of my best DPSes, yet somehow, his pixel eludes me. I think it’s because it’s really hard to get two low-health targets close enough for the splash of the helix rockets.)
-Bastion: Charge! (I don’t play Bastion either and I also have NO IDEA how anyone kills anything with that ult anyway. I’ve tried. I just don’t get it.)
-Junkrat: Mine Like A Steel Trap (I don’t play games to be subjected to physics and geometry homework.)
-Widowmaker: Did That Sting? and Smooth As Silk (Hahahahahaha me playing Widowmaker hahahahaha)
-Doomfist: Air Strike and Cratered (Once again: don’t play Doomfist.)
-Ashe: Served Up and Short Fuse (I don’t play Ashe -enough- in this case to get her achieves. I actually really want to play her more, she’s really fun.)
Tank:
-Orisa: Halt State (I need more practice with her Halt in general because I’m so bad with it, but also, pulling into 1000 damage with a single Halt, and environmental kills not counting, basically makes this REQUIRE luck and a D.Va to pull off, and it’s frankly kinda ridiculous.)
Support:
-Baptiste: Window of Opportunity and Stand By Me (I know Window is either broken or just insanely impossible to get. I have no idea why Stand By Me hasn’t popped yet. I’ve used that damn field so many times to save us from D.Va bombs and Junk tires and more. I can only assume it’s also bugged.)
Misc:
-Archives: Distinguished Service and Hurricane (Legendary Uprising is all but impossible since the various hero nerfs and the fact that it wasn’t re-balanced like Retribution was makes this one require absolute perfection. Hurricane is just expecting Genji mains to be competent, which is a futile effort and we all know it.)
Any Doomfist spray or the Zenyatta pixel and I’ve had roughly around 14-18 hours on each character
Most DPS ones (cuz I hate dps), a few tank ones (cuz I don’t play tank) and I’m only missing baptiste’s window and zen’s discord one. I don’t expect to get them though, they’re too hard to get.
I’m missing a bunch,
Cute:
Trob, Dva, Sig, Hammond, Doom, Bapt.
Pixel:
Reaper, Zen, Lucio, Doom, Bapt.
I think its actually easier to get achievements the lower the rank you are. People are slower to react and are more out of position. If you die to a Dva bomb in masters, that does not look good at all.
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Stand in the back and shoot at the enemy is his entire gameplay. Why would I pick a support instead of Hanzo or an Ashe to do that?
Same here, annoyingly though I did get Baps pixel spray on an alt account.
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Basically the ones from crap modes. Like Mei snowball stuff. And i think Uprising Legendary. The characters are crap for it.
Uprising: Expert and Legendary. I just did “Handle With Care” (Keep Payload over 80% Health on Hard)
Retribution: Legendary and Expert with No Incapacitations
Storm Rising: Expert, Legendary, and Legendary (All Heroes) With No Incapacitations
Junkenstein: “Unscathed” (Endless Hard with No Damage to Door), “Survivor” (4 Bonus Waves on Endless Expert),
Doomfist: “Cratered”
Baptiste: “Window of Opportunity”
Because you wanna also have good self heal and be able to heal allies lol. Zenyatta is legit just a DPS but he can do more.
This doesn’t only work for the enemies, but your allies too. Bap’s immort one would be very easy if my teammates suck. We all get caught in a grav, the enemies waste all their ults, ez. But noooo, our D.va knows it’s coming and eats the grav or something to that respect. Sometimes your teammates being smart hurts you the most in the end.
Well on the plus side I can cross 76’s pixel spray off the list.
Downside, got it in the SECOND match against a damn Baptiste smurf despite reporting him already. (Seriously no bronze Bap gets 44 elims/56% kill participation. Blizz, get your sh!t together.)
I’ve got every other character achievement except Baptiste’s cutie and pixel.
Only missing a few event sprays but I don’t mind them too much as there’s no trophy assigned to them and only give an in game spray.
Also hitting D.Va mid demeching animation doesn’t count.
Believe me I know… 
Baptiste cute and Orissa pixel
I have for all the achievments for the events but I don’t have a lot of hero achievments…
But talking only about heroes I consider my mains right now I have hem all for most of them (Orisa, Hammond, Diva, Widowmaker, Sombra, Brigitte and MOira) and am only missing the one where “kill 3 ppl without touching the floor” as Lucio.