Primal Frostburn Gloves

Are there any builds that can actually use a Primal Frostburn?

ya you can make LoN/LoD gem cold WoL build, cold dh sentry multishot-cluster, etc. So yes there are off the main builds for cold items…
Similar to something like this: https://us.diablo3.com/en/profile/Blackarrows-1814/hero/71155663

How do they compare to the standard build. Or are they just fun builds to try

These are just different and more fun oriented. Fire does more damage than cold skills…

You could make a LoD Tempest Rush build using Flurry rune.