Need Help with Item

I was wanted to send a item to my friend how do I do that on the PC

On PC, this is only possible if the other person was in your game when the item first dropped, and then for only 2 hours after it dropped.

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To add to what VitaKaninen has stated, you cannot “send” items to Friends on PC. When they’re in your game and the item is not Account Bound you drop the item(s) on the ground and they pick them up.